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Please read through this chapter before attempting to build a PC of your own. Okay, you re eager to get going and a chapter all about safety doesn t sound all that compelling, but your safety and the safety of those around you are of paramount importance. We don t want to lose any of you in mid-build! Also of great importance is the safety of the PC components you have bought. A millisecond s carelessness can cost you hundreds of dollars.

In this chapter you have learned how to use the final tool in the XSQL arsenal serializers. They are especially apt for the creation of binary data. By using serializers, you can create any kind of data presentation that you wish. Often, this will mean leveraging existing tools such as FOP, but you are also free to write the binary formats directly from the ground up. You now know all you need to know to easily create robust applications by using XSQL. You probably learned a number of new paradigms along the way, but hopefully you can now see how XSQL can make applications easily. Have fun!

are the energies of the electron localized to sites A and B, respectively. These are only approximately equal to the energies of the orbitals of the isolated sites since heff includes the shielded nuclear in uence of the other site. If sites A and B have identical orbitals, then hAA hBB . In other words, the orbital energies are the same. The intrinsic interaction integral hAB wA 1 heff 1 wB 1 dt1 3X8

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whose strong local elds may be useful for precise, photoinitiated processes in nanostructured arrays [354] The equations that describe the frequencies of the plasmons in nanoparticles are similar, but not identical, to the quantum theory equations that describe the energies of electrons in atoms and molecules (eg, Appendix D); this means that nanophotonic structures can be modeled in quantum-theoretic terms, rather than in classical optics terms The type of plasmon that exists on a surface is directly related to the surface s topology, for example, a nanosized pore in metallic foil or the curvature of a nanoscale gold sphere When light of a de ned frequency interacts with a plasmon that oscillates at a compatible frequency, the energy from the light is captured by the plasmon, converted into electrical energy that propagates through the nanostructure, and ultimately reconverted back to light [265, 294].

Figure 2.3 (Continued)

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Dielectric materials have modest refractive indices and, as a result, the range wave vectors achievable at optical frequencies have held back the scaling of dielectric optical components Fortunately metallic, metallodielectric, and metal/semiconductor hybrid photonic structures have the capability to signi cantly alter this situation [249] These structures support surface and interface plasmons that o er the ability to localize, extract, and enhance electromagnetic elds at metallodielectric interfaces and in nanostructures The unusual dispersion properties of metals near the plasmon resonance enables excitation of surface modes and resonant modes in nanostructures that access a very large range of wave vectors over a narrow frequency range This feature constitutes a critical design principle for light localization below the freespace wavelength and opens the path to truly nanophotonic and plasmonic optical devices Thus, truly nanophotonic components and systems based on such materials now appear to be viable [249].

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(9.35)

Another nanoscale arrangement that can sustain surface plasmons are metal nanoparticles [355, 356] In metal nanoparticles, the 3D con nement of the electrons leads to well-de ned surface plasmon resonances at speci c frequencies It has been established that light at the surface plasmon resonance frequencies interacts strongly with metal particles and excites a collective motion of the conduction electrons, or plasmon [357] These resonance frequencies are typically in the visible or infrared part of the spectrum for gold and silver nanoparticles For particles with a diameter much smaller than the wavelength of the exciting light, plasmon excitations produce an oscillating electric dipole eld resulting in a resonantly enhanced nonpropagating electromagnetic near eld (see Section 562) close to the particle surface [142].

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